A 400 nm femtosecond laser was used to ablate the surface of a high-pressure and high-temperature diamond, and subwavelength surface micro structures with a period of 100 nm were achieved. A variety of micro-nano composite surface structures were prepared by changing the polarization direction and laser scanning direction. By dynamically adjusting the laser polarization and the laser scanning tracks, a maskless direct writing fabrication of micro-nano complex structures was realized. The micro-nano patterning on an ultra-hard and super-stabile diamond provides a new idea for the preparation of friction reducing surfaces, nano imprint transfer templates, surface enhanced Raman scattering test substrates, and micro-nano optical structures.